Micropore Decoration with Bidentate Lewis Acids: Spontaneous Assembly of 1,2-Bis(chloromercurio)tetrafluorobenzene. Academic Article uri icon

abstract

  • Dimethyl sulfoxide templates the assembly of 1,2-bis(chloromercurio)tetrafluorobenzene (1) into an internally Lewis acidic microporous solid of composition 1 small middle dot(DMSO)(3) (2). The channels of 2 contain both chelated and solvate DMSO molecules (omitted in the drawing for clarity), which can be partly exchanged with water molecules. The hydration-dehydration of the resulting compound is reversible.

published proceedings

  • Angew Chem Int Ed Engl

author list (cited authors)

  • Tschinkl, M., Schier, A., Riede, J., & Gabbai, F. P.

citation count

  • 47

complete list of authors

  • Tschinkl, M||Schier, A||Riede, J||Gabbai├», FP

publication date

  • December 1999

publisher