Dimerization of the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] via mercurophilic interactions.
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abstract
In the crystalline state, the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] forms cofacial dimers which are held by two mercurophilic interactions of 3.51 A. In this form, the complex displays an intense photoluminescence with a sharp emission centered at 480 nm.