Electrophilic double-sandwiches formed by interaction of [Cp(2)Fe] and [Cp(2)Ni] with the tridentate lewis acid [(o-C(6)F(4)Hg)(3)]. Academic Article

abstract

• A sandwich in a sandwich: Electrophilic double-sandwich compounds are readily formed by interaction of ferrocene and nickelocene with the tridentate Lewis acid 1 (see scheme; C gray, F light green, Hg orange, M dark green). These new supramolecules result from interactions between the mercury centers of 1 and the C5H5 rings of the metallocenes. Surprisingly, the nickelocene derivative is dark red and air stable.

authors

• Gabbai, Francois

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 3

author list (cited authors)

• Haneline, M. R., & Gabbai, F. P.

citation count

• 60

complete list of authors

• Haneline, Mason R||Gabbaiï, François P

publication date

• October 2004

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Crystallography, X-Ray
• Electrochemistry
• Iron
• Mercury
• Models, Molecular
• Molecular Structure
• Nickel
• Organometallic Compounds

PubMed Central ID

• 15484255

Digital Object Identifier (DOI)

• 10.1002/anie.200461152

start page

• 5471

end page

• 5474

volume

• 43

issue

• 41

URL

• http://dx.doi.org/10.1002/anie.200461152