Anion-controlled switching of an Xligand into a Zligand: coordination non-innocence of a stiboranyl ligand. Academic Article uri icon

abstract

  • The tetravalent platinum stiboranyl complex [(o-(Ph2P)C6H4)2(o-C6Cl4O2)Sb]PtCl2Ph (2) has been synthesized by reaction of [(o-(Ph2P)C6H4)2SbClPh]PtCl (1) with o-chloranil. In the presence of fluoride anions, the stiboranyl moiety of 2 displays non-innocent behavior and is readily converted into a fluorostiborane unit. This transformation, which is accompanied by elimination of a chloride ligand from the Pt center, results in the formation of [(o-(Ph2P)C6H4)2(o-C6Cl4O2)SbF]PtClPh (3). Structural, spectroscopic, and computational studies show that the conversion of 2 into 3 is accompanied by a cleavage of the covalent Pt-Sb bond present in 2 and formation of a longer and weaker PtSb interaction in 3. These results show that this new Pt-Sb platform supports the fluoride-induced metamorphosis of a stiboranyl Xligand into a stiborane Zligand.

published proceedings

  • Angew Chem Int Ed Engl

altmetric score

  • 2.35

author list (cited authors)

  • Ke, I., Jones, J. S., & Gabbai, F. P.

citation count

  • 73

complete list of authors

  • Ke, Iou-Sheng||Jones, James S||Gabbaiï, François P

publication date

  • March 2014

publisher