SPECTROSCOPIC STUDIES OF NICKEL AND IRON CLUSTERS AT 12-K
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abstract
The electronic and far-infrared spectra of nickel and iron clusters trapped in argon matrices at 12 K are reported. The 3 antisymmetric stretching frequencies for Ni3 and Fe3 were observed for the first time at 198 and 180 cm-1, respectively. The fr and frr force constants for Ni3 are calculated to be 0.80 and 0.13 mdyn/, respectively. For Fe3 these are 0.67 and 0.13 mdyn/. 1987 American Institute of Physics.