DYNAMICS OF THE DUAL FLUORESCENCES OF PARA-DIMETHYLAMINOBENZONITRILE Academic Article

abstract

• The time-resolved dual-fluorescence picosecond kinetics of p-dimethylaminobenzonitrile in dodecanol, decanol, hexanol and methanol were studied. Pulse-limited rise times were found in the emission of the b* state which feeds directly the rise time of a* state emission. We found that the b* state fluorescence decay times follow the solvent viscosity. The a* state fluorescence kinetics vary with solvent and temperature, which suggests either thermally assisted intersystem crossing to a solvated triplet or thermally activated internal conversion to the ground state. 1982.

authors

• Rentzepis, Peter

published proceedings

• JOURNAL OF PHOTOCHEMISTRY

author list (cited authors)

• HUPPERT, D., RAND, S. D., RENTZEPIS, P. M., BARBARA, P. F., STRUVE, W. S., & GRABOWSKI, Z. R.

citation count

• 6

complete list of authors

• HUPPERT, D||RAND, SD||RENTZEPIS, PM||BARBARA, PF||STRUVE, WS||GRABOWSKI, ZR

publication date

• January 1982

publisher

• Elsevier  Publisher

published in

• Journal of Photochemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/0047-2670(82)80010-5

start page

• 89

end page

• 95

volume

• 18

issue

• 1

URL

• http://dx.doi.org/10.1016/0047-2670(82)80010-5

user-defined tag

• 13 Climate Action