Picosecond spectroscopy of charge-transfer processes. Photochemistry of anthracene-tetranitromethane EDA complexes
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The temporal sequence of events that follow 532 nm excitation of electron donor-acceptor, EDA, complexes of several substituted anthracenes with tetranitromethane is monitored by means of picosecond spectroscopy. Excitation of the charge-transfer band of these EDA complexes produces high yields of 1 : 1 adducts. Absorption spectra and kinetics of the transient species involved in these photochemical reactions provide the basis for elucidation of the reaction mechanism following charge-transfer excitation to the ion pairs. 1984.
author list (cited authors)
Masnovi, J. M., Huffman, J. C., Kochi, J. K., Hilinski, E. F., & Rentzepis, P. M.
complete list of authors
Masnovi, JM||Huffman, JC||Kochi, JK||Hilinski, EF||Rentzepis, PM