Electron transfer and dissociation mechanism of ferrioxalate: A time resolved optical and EXAFS study Academic Article

abstract

• By means of ultrafast optical transient spectroscopy and EXAFS we have measured the transient spectra kinetics and Fe-O bond length of the ferrioxalate redox reaction transients. Based on Fe-O bond distances of the photoredox intermediates and quantum chemistry DFT and H-F calculations we propose a photoredox mechanism where photodissociation precedes electron transfer. 2007 Elsevier B.V. All rights reserved.

authors

• Rentzepis, Peter

published proceedings

• CHEMICAL PHYSICS LETTERS

author list (cited authors)

• Chen, J., Zhang, H., Tomov, I. V., Ding, X., & Rentzepis, P. M.

citation count

• 29

complete list of authors

• Chen, Jie||Zhang, Hua||Tomov, Ivan V||Ding, Xunliang||Rentzepis, Peter M

publication date

• March 2007

publisher

• Elsevier  Publisher

published in

• CHEMICAL PHYSICS LETTERS  Journal

Digital Object Identifier (DOI)

• 10.1016/j.cplett.2007.02.005

start page

• 50

end page

• 55

volume

• 437

issue

• 1-3

URL

• http://dx.doi.org/10.1016/j.cplett.2007.02.005