Electron transfer and dissociation mechanism of ferrioxalate: A time resolved optical and EXAFS study
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By means of ultrafast optical transient spectroscopy and EXAFS we have measured the transient spectra kinetics and Fe-O bond length of the ferrioxalate redox reaction transients. Based on Fe-O bond distances of the photoredox intermediates and quantum chemistry DFT and H-F calculations we propose a photoredox mechanism where photodissociation precedes electron transfer. © 2007 Elsevier B.V. All rights reserved.
author list (cited authors)
Chen, J., Zhang, H., Tomov, I. V., Ding, X., & Rentzepis, P. M.
complete list of authors
Chen, Jie||Zhang, Hua||Tomov, Ivan V||Ding, Xunliang||Rentzepis, Peter M