Electron transfer and dissociation mechanism of ferrioxalate: A time resolved optical and EXAFS study Academic Article uri icon

abstract

  • By means of ultrafast optical transient spectroscopy and EXAFS we have measured the transient spectra kinetics and Fe-O bond length of the ferrioxalate redox reaction transients. Based on Fe-O bond distances of the photoredox intermediates and quantum chemistry DFT and H-F calculations we propose a photoredox mechanism where photodissociation precedes electron transfer. 2007 Elsevier B.V. All rights reserved.

published proceedings

  • Chemical Physics Letters

author list (cited authors)

  • Chen, J., Zhang, H., Tomov, I. V., Ding, X., & Rentzepis, P. M.

citation count

  • 28

complete list of authors

  • Chen, Jie||Zhang, Hua||Tomov, Ivan V||Ding, Xunliang||Rentzepis, Peter M

publication date

  • March 2007