THE GROUND-STATE OXYGEN-BENZOPHENONE COMPLEX Academic Article

abstract

• In studies of the photoproduction of triplet excited benzophenone in cyclohexane by picosecond absorption spectroscopy (266-nm pump), it is shown that the presence of dissolved oxygen at 1 atm of pressure decreases the triplettriplet 347-nm transition by 50% in less than 25 ps, indicating the presence of a stable ground-state oxygen-benzophenone complex. This work suggests that there may be a need to reevaluate any triplet risetime and quantum yield experiments performed on aromatic/carbonyl compounds in nondeoxygenated solutions. 1986, American Chemical Society. All rights reserved.

authors

• Rentzepis, Peter

published proceedings

• JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

author list (cited authors)

• HUTCHINSON, J. A., DIBENEDETTO, J., & RENTZEPIS, P. M.

citation count

• 5

complete list of authors

• HUTCHINSON, JA||DIBENEDETTO, J||RENTZEPIS, PM

publication date

• October 1986

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

Digital Object Identifier (DOI)

• 10.1021/ja00281a012

start page

• 6517

end page

• 6521

volume

• 108

issue

• 21

URL

• http://dx.doi.org/10.1021/ja00281a012