Picosecond absorption studies on the excited state of (.mu.-oxo)-bis[(tetraphenylporphinato)iron(III)] Academic Article uri icon

abstract

  • We have measured the kinetics and spectra of the intermediates of (μ-oxo)bis[(tetraphenylporphinato)iron(III)] in various solvents. The spectra of the intermediate species were measured at various intervals of time from -100 to 4.3 ns after excitation with a 532- or 355-nm 25-ps pulse. The intermediate state, possibly a cation radical, was assigned to a monomer that forms the photodissociated pair TPPFeII+ + TPPFeIII-O- and yields a small amount of disproportionation reaction products, FeIITPP and TPPFeIV=O. © 1988, American Chemical Society. All rights reserved.

author list (cited authors)

  • Guest, C. R., Straub, K. D., Hutchinson, J. A., & Rentzepis, P. M.

citation count

  • 20

complete list of authors

  • Guest, CR||Straub, KD||Hutchinson, JA||Rentzepis, Peter M

publication date

  • August 1988