PRESSURE-DEPENDENCE ON EXCITED-STATE INTRAMOLECULAR ELECTRON-TRANSFER DYNAMICS IN POLAR-SOLVENTS
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The effect of pressure on intramolecular electron transfer of p-(9-anthryl)-N,N-dimethylaniline (ADMA) has been studied by means of picosecond time-resolved fluorescence. It is shown that the intramolecular electron-transfer rate is related to the longitudinal dielectric relaxation time. 1988 American Chemical Society.