Reorientation of hydrogen-bonded solvents around a large dipole Academic Article

abstract

• Using picosecond spectroscopy, we find rise times R 20 ps for p-dimethylaminobenzonitrile S2 S0 fluorescence in the weakly hydrogen-bound alcohols 2,2,2-trifluoroethanol and 2-fluoroethanol. Since we previously obtained R 40 ps in methanol and ethanol, this provides evidence that hydrogen-bonding-retarded solvent reorientation largely governs the fluorescence in these solvents. 1974.

authors

• Rentzepis, Peter

published proceedings

• Chemical Physics Letters

author list (cited authors)

• Struve, W. S., & Rentzepis, P. M.

citation count

• 38

complete list of authors

• Struve, WS||Rentzepis, PM

publication date

• November 1974

publisher

• Elsevier  Publisher

published in

• CHEMICAL PHYSICS LETTERS  Journal

Digital Object Identifier (DOI)

• 10.1016/0009-2614(74)80127-2

start page

• 23

end page

• 27

volume

• 29

issue

• 1

URL

• http://dx.doi.org/10.1016/0009-2614(74)80127-2