Ultrafast Time-Resolved Transient Structures of Solids and Liquids Studied by Means of X-ray Diffraction and EXAFS Academic Article uri icon

abstract

  • Picosecond and nanosecond transient structures have been observed directly using time-resolved X-ray diffraction and absorption. These experiments provide insight on the evolution of transient molecular structure on the atomic length scale during the course of a chemical reaction. Recent advances in the generation of short X-ray pulses and detectors have made time-resolved X-ray studies a reality. We discuss a few of the vast number of possible time-resolved structure studies in solids and fluids. Ultrafast relaxation dynamics of crystal lattice structures induced by picosecond and nanosecond laser pulses have been observed by means of time-resolved picosecond and nanosecond X-ray diffraction. Lattice deformation with 10 ps and 10-3 Å resolution have been performed. The picosecond X-ray system, which we have used, is described, and its application to time-resolved ultrafast X-ray diffraction in crystals and EXAFS in liquids is discussed. © 1999 American Chemical Society.

author list (cited authors)

  • Tomov, I. V., Oulianov, D. A., Chen, P., & Rentzepis, P. M.

citation count

  • 51

publication date

  • August 1999