Dissolved iron and iron isotopes in the southeastern Pacific Ocean
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AbstractThe Southeast Pacific Ocean is a severely understudied yet dynamic region for trace metals such as iron, since it experiences steep redox and productivity gradients in upper waters and strong hydrothermal iron inputs to deep waters. In this study, we report the dissolved iron (dFe) distribution from seven stations and Fe isotope ratios (56Fe) from three of these stations across a nearzonal transect from 20 to 27S. We found elevated dFe concentrations associated with the oxygendeficient zone (ODZ), with light 56Fe implicating porewater fluxes of reduced Fe. However, temporal dFe variability and rapid 56Fe shifts with depth suggest gradients in ODZ Fe source and/or redox processes vary over shortdepth/spatial scales. The dFe concentrations decreased rapidly offshore, and in the upper ocean dFe was controlled by biological processes, resulting in an Fe:C ratio of 4.2mol/mol. Calculated vertical diffusive Fe fluxes were greater than published dust inputs to surface waters, but both were orders of magnitude lower than horizontal diffusive fluxes, which dominate dFe delivery to the gyre. The 56Fe data in the deep sea showed evidence for a 0.2 Antarctic Intermediate Water endmember and a heavy 56Fe of +0.55 for distally transported hydrothermal dissolved Fe from the East Pacific Rise. These heavy 56Fe values were contrasted with the nearcrustal 56Fe recorded in the hydrothermal plume reaching Station ALOHA in the North Pacific. The heavy hydrothermal 56Fe precludes a nanopyrite composition of hydrothermal dFe and instead suggests the presence of oxides or, more likely, binding of hydrothermal dFe by organic ligands in the distal plume.
