Displacement of the heptane solvent from (eta(5)-C5H5)Re(CO)(2)(heptane): A flash photolysis study using infrared detection Academic Article

abstract

• The displacement of the heptane solvent molecule from the (5-C5H5)Re(CO)2(heptane) complex by a variety of ligands is studied. The substitution reaction proceeds through an Id mechanism since changes in the electronic and steric properties of the incoming ligand do not influence the reaction rate significantly. Activation parameters suggest a lower limit of 57.3 0.9 kJ/mol for the strength of the Re-heptane interaction. 2005 Elsevier B.V. All rights reserved.

authors

• Bengali, Ashfaq

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• Bengali, A. A.

citation count

• 8

complete list of authors

• Bengali, AA

publication date

• January 2005

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Infrared Spectroscopy
• Photochemistry
• Reaction Kinetics
• Rhenium

Digital Object Identifier (DOI)

• 10.1016/j.jorganchem.2005.07.056

start page

• 4989

end page

• 4992

volume

• 690

issue

• 21-22

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fj.jorganchem.2005.07.056