Self-capacitance of a Thomas-Fermi nanosphere
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abstract
We calculate the self-capacitance and charging energy of a spherical nanoparticle in the Thomas-Fermi approximation. The result is CTF=C0[1 -p-1tanh p]/[1-(1--1)p-1tanh p], with CTFC0. Here C0= 4 0R is the classical geometrical value, p = R/l is the ratio of the particle radius R to the Thomas-Fermi screening length l, and is the material dielectric constant. The addition of surface localized states drives C toward C0. These results should be relevant to tunneling spectroscopy studies of giant carbon onions and "large" semiconductor nanocrystals that do not require a full quantum treatment. 2000 American Institute of Physics.