Enthalpies of water + methanol mixtures between 180 K and 320 K
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Enthalpy increments relative to 298.15 K were measured using a thermoelectric flow calorimeter for six water + methanol mixtures between 180 K and 320 K. Excess Gibbs energies were derived as a function of temperature and composition from the measured enthalpies and vapor-liquid equilibrium results reported in the literature. The excess Gibbs energies are calculated relative to hypothetical liquid water below 273.15 K; the properties of the hypothetical liquid also are reported. © 1993.
author list (cited authors)
Cochran, S. W., Holste, J. C., Marsh, K. N., Gammon, B. E., & Hall, K. R.