DENSITY OF AN EQUIMOLAR MIXTURE OF ETHANE AND METHYL-CHLORIDE
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We have measured the density of an equimolar gas mixture of C2H6CH3Cl between 323.15 and 473.15 K at pressures to 14.0 MPa. Interaction second virial coefficients and dewpoint pressures are extracted from the measurements. Intermolecular force constants for the LennardJones and Stockmayer models are determined optimally for like and unlike pair interactions. Recent methods of prediction for second virial coefficients, both pure and interaction, are tested against experiment. Copyright 1985 American Institute of Chemical Engineers