Electrical and material characteristics of the sub 5 nm hafnium doped tantalum oxide high K film
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abstract
Ultra-thin films (less than 5nm) of hafnium doped tantalum oxide (Hf-doped TaOx) high-k dielectric films were deposited by reactive sputtering as alternative gate dielectric materials for future CMOS devices. A film with an equivalent oxide thickness (EOT) of 13 and a leakage current density of 7_10-3A/cm2 at -1 V relative to the flat-band voltage has been obtained. The Hf-doped TaOx film is composed of HfOx and TaOx. The binding energy of Ta 4f in the film shifts to a lower value with the inclusion of the Hf in the film due to charge transfer among elements. The Hf-doped film remains amorphous after 700C N2 or O2 annealing. The N2 annealed film has a lower EOT, a thinner interfacial layer, and a higher leakage current than the O2 annealed film. 2004 IEEE.