Photolysis of CBr4 and its transient solvent stabilized (CBr3+//Br-)solv ion pair. Academic Article

abstract

• In this paper we describe the mechanism of the photodissociation of CBr4 in various solvents. We have monitored and identified the intermediate species and determined the growth and decay rates of the excited states and metastable species formed during the photodissociation process by means of ultrafast time-resolved spectroscopy. On the basis of the experimental data presented in this paper, the observed transient spectra and species have been assigned to the stabilized solvated ion pair (CBr3+//Br-)solv.

authors

• Rentzepis, Peter

published proceedings

• J Phys Chem A

author list (cited authors)

• Zhang, H., Dvornikov, A. S., & Rentzepis, P. M.

citation count

• 8

complete list of authors

• Zhang, Hua||Dvornikov, AS||Rentzepis, PM

publication date

• July 2005

publisher

• American Chemical Society (ACS)  Publisher

published in

• The Journal of Physical Chemistry A: Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory  Journal

keywords

• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 16833933

Digital Object Identifier (DOI)

• 10.1021/jp050221x

start page

• 5984

end page

• 5988

volume

• 109

issue

• 27

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fjp050221x