Selectivity and delignification kinetics for oxidative short-term lime pretreatment of poplar wood, Part I: Constant-pressure.
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Kinetic models applied to oxygen bleaching of paper pulp focus on the degradation of polymers, either lignin or carbohydrates. Traditionally, they separately model different moieties that degrade at three different rates: rapid, medium, and slow. These models were successfully applied to lignin and carbohydrate degradation of poplar wood submitted to oxidative pretreatment with lime at the following conditions: temperature 110-180C, total pressure 7.9-21.7 bar, and excess lime loading of 0.5 g Ca(OH)2 per gram dry biomass. These conditions were held constant for 1-6 h. The models properly fit experimental data and were used to determine pretreatment selectivity in two fashions: differential and integral. By assessing selectivity, the detrimental effect of pretreatment on carbohydrates at high temperatures and at low lignin content was determined. The models can be used to identify pretreatment conditions that selectively remove lignin while preserving carbohydrates. Lignin removal50% with glucan preservation90% was observed for differential glucan selectivities between 10 and 30 g lignin degraded per gram glucan degraded. Pretreatment conditions complying with these reference values were preferably observed at 140C, total pressure14.7 bars, and for pretreatment times between 2 and 6 h depending on the total pressure (the higher the pressure, the less time). They were also observed at 160C, total pressure of 14.7 and 21.7 bars, and pretreatment time of 2 h. Generally, at 110C lignin removal is insufficient and at 180C carbohydrates do not preserve well.
