Dehydrogenation of a tertiary amine-borane by a rhenium complex Academic Article uri icon

abstract

  • Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

author list (cited authors)

  • Muhammad, S., Moncho, S., Brothers, E. N., & Bengali, A. A.

publication date

  • January 1, 2014 11:11 AM