Dehydrogenation of a tertiary amine-borane by a rhenium complex. Academic Article uri icon

abstract

  • Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Muhammad, S., Moncho, S., Brothers, E. N., & Bengali, A. A

citation count

  • 20

complete list of authors

  • Muhammad, Sohail||Moncho, Salvador||Brothers, Edward N||Bengali, Ashfaq A

publication date

  • June 2014