SUPERPARAMAGNETIC NANOPARTICLES AND CLUSTERS OF A FEW FE ATOMS IN AMORPHOUS FE0.33ZR0.67 ALLOYS
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A paramagnetic amorphous Fe0.33Zr0.67 alloy has been studied with Mossbauer spectroscopy and SQUID magnetometry. Low-field magnetization measurements revealed the existence of superparamagnetic nanoparticles of thousands of mu B embedded in the alloy with a blocking temperature of 50 K. A saturation of local moments (15.9 mu B), possibly clusters of a few Fe ions, is observed at 4.6 K around 10 kOe. The temperature dependence of the high-field magnetic susceptibility of Fe0.33Zr0.67 is interpreted with Curie's law for these Fe clusters and nanoparticles.