The objective of this paper is to define and derive a dimensionless number as a function of material properties and process parameters to quantify the extent (magnitude) of thermocapillary flow in pulsed laser micropolishing (PLμP). Experimental work has shown that thermocapillary flow can tremendously reduce surface roughness (smoothing effect) although it inevitably introduces additional surface features (roughening effect) at the same time. Both the smoothing and roughening effects increase as the extent of thermocapillary flow increases. The extent of thermocapillary flow is the bridge from the available information (i.e., initial surface profile, material properties, and process parameters) to the polished surface profile to be predicted. A dimensionless number, called the normalized average displacement of a liquid particle in a single laser pulse, is proposed and derived via analytical heat transfer and fluid flow equations. The calculated normalized displacement is found to be proportional to the measured slope of the introduced features on Ti6Al4V surface polished with various process parameters, which indicates that the dimensionless number successfully describes the extent of thermocapillary flow. The normalized average displacement will be very useful for prediction of polished surface profile and hence parameter selection and process optimization in the future.