Rotational analysis of the (57,0) band of the D1(u) <- X0(g)(+) triplet-singlet transition in Hg-2 produced in a free-jet expansion beam
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abstract
Analysis of the rotational structure of the (57, 0) vibrational band of the D 1u X 0g+ transition in Hg2 (natural abundance) is presented. From the analysis, the Bv=57, Bv=0, Be and Be rotational constants of the 398Hg2, 400Hg2, 402Hg2, 404Hg2 and 406Hg2, as well as the Re = 2.715 and Re = 3.605 bond lengths for the excited and ground electronic energy states involved in the transition are determined. 2008 Elsevier B.V. All rights reserved.