An exceptionally stable, porphyrinic Zr metal-organic framework exhibiting pH-dependent fluorescence. Academic Article uri icon

abstract

  • A reaction between a Zr(IV) salt and a porphyrinic tetracarboxylic acid leads to a metal-organic framework (MOF) with two types of open channels, representing a MOF featuring a (4,8)-connected sqc net. The MOF remains intact in both boiling water and aqueous solutions with pH ranging from 1 to 11, a remarkably extensive pH range that a MOF can sustain. Given its exceptional stability and pH-dependent fluorescent intensity, the MOF can potentially be applied in fluorescent pH sensing.

author list (cited authors)

  • Jiang, H., Feng, D., Wang, K., Gu, Z., Wei, Z., Chen, Y., & Zhou, H

complete list of authors

  • Jiang, Hai-Long||Feng, Dawei||Wang, Kecheng||Gu, Zhi-Yuan||Wei, Zhangwen||Chen, Ying-Pin||Zhou, Hong-Cai

publication date

  • January 1, 2013 11:11 AM