A series of highly stable mesoporous metalloporphyrin Fe-MOFs. Academic Article uri icon

abstract

  • A series of mesoporous metalloporphyrin Fe-MOFs, namely PCN-600(M) (M = Mn, Fe, Co, Ni, Cu), have been synthesized using the preassembled [Fe3O(OOCCH3)6] building block. PCN-600 exhibits a one-dimensional channel as large as 3.1 nm and the highest experimental pore volume of 1.80 cm(3)g(-1) among all the reported porphyrinic MOFs. It also shows very high stability in aqueous solutions with pH values ranging from 2-11 and is to our knowledge the only mesoporous porphyrinic MOF stable under basic aqueous conditions. PCN-600(Fe) has been demonstrated as an effective peroxidase mimic to catalyze the co-oxidation reaction.

author list (cited authors)

  • Wang, K., Feng, D., Liu, T., Su, J., Yuan, S., Chen, Y., ... Zhou, H.

complete list of authors

  • Wang, Kecheng||Feng, Dawei||Liu, Tian-Fu||Su, Jie||Yuan, Shuai||Chen, Ying-Pin||Bosch, Mathieu||Zou, Xiaodong||Zhou, Hong-Cai

publication date

  • January 1, 2014 11:11 AM