An unusual case of symmetry-preserving isomerism.
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Two isomeric phases of the NbO-type structure have been discovered: PCN-16 (alpha phase) and PCN-16' (beta phase), and gas sorption studies revealed that the alpha phase possesses a larger surface area, leading to higher hydrogen and methane storage capacity as compared with the beta phase.
author list (cited authors)
Sun, D., Ma, S., Simmons, J. M., Li, J., Yuan, D., & Zhou, H.
complete list of authors
Sun, Daofeng||Ma, Shengqian||Simmons, Jason M||Li, Jian-Rong||Yuan, Daqiang||Zhou, Hong-Cai