Topology-guided design of an anionic bor-network for photocatalytic [Ru(bpy)3](2+) encapsulation. Academic Article uri icon

abstract

  • An anionic metal-organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlying bor-net is realized by the use of a tetrahedral [In(COO)4](-) node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage and 1D channel make PCN-99 an excellent matrix to encapsulate the photocatalytic [Ru(bpy)3](2+).

published proceedings

  • Chem Commun (Camb)

altmetric score

  • 0.25

author list (cited authors)

  • Wang, X., Lu, W., Gu, Z., Wei, Z., & Zhou, H.

citation count

  • 51

complete list of authors

  • Wang, Xuan||Lu, Weigang||Gu, Zhi-Yuan||Wei, Zhangwen||Zhou, Hong-Cai

publication date

  • January 2016