Topology-guided design of an anionic bor -network for photocatalytic [Ru(bpy) 3 ] 2+ encapsulation
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An anionic metal-organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlying bor-net is realized by the use of a tetrahedral [In(COO)4](-) node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage and 1D channel make PCN-99 an excellent matrix to encapsulate the photocatalytic [Ru(bpy)3](2+).
author list (cited authors)
Wang, X., Lu, W., Gu, Z., Wei, Z., & Zhou, H.