Unprecedented activation and CO2 capture properties of an elastic single-molecule trap.
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abstract
The activation and CO2 capture properties of a microporous metal-organic framework with elastic single-molecule traps were systematically investigated. This material shows a unique low-energy gas-purge activation capability, high CO2 adsorption selectivities over various gases and optimized working capacities per energy of 2.9 mmol kJ(-1) at 128 C.