A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules. uri icon

abstract

  • A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).

published proceedings

  • Inorg Chem

altmetric score

  • 15

author list (cited authors)

  • Chen, B., Ma, S., Hurtado, E. J., Lobkovsky, E. B., & Zhou, H.

citation count

  • 219

complete list of authors

  • Chen, Banglin||Ma, Shengqian||Hurtado, Eric J||Lobkovsky, Emil B||Zhou, Hong-Cai

publication date

  • October 2007