[(Tp)(8)(H(2)O)(6)Cu(II) (6)Fe(III) (8)(CN)(24)](4+): a cyanide-bridged face-centered-cubic cluster with single-molecule-magnet behavior. Academic Article uri icon

abstract

  • A box of magnetic tricks: By using the anionic precursor [(Tp)Fe(CN) 3]- (Tp-= hydrotris(pyrazolyl)borate), the title compound, which is a new face-centered-cubic cluster, has been synthesized (see structure; red Fe, turquoise Cu, orange B, gray C, blue N, dark red O). Magnetic studies show that it exhibits single-molecule-magnet behavior with substantial axial magnetic anisotropy (D = -0.16cm-1).

published proceedings

  • Angew Chem Int Ed Engl

author list (cited authors)

  • Wang, S., Zuo, J., Zhou, H., Choi, H. J., Ke, Y., Long, J. R., & You, X.

citation count

  • 222

complete list of authors

  • Wang, Shi||Zuo, Jing-Lin||Zhou, Hong-Cai||Choi, Hye Jin||Ke, Yanxiong||Long, Jeffrey R||You, Xiao-Zeng

publication date

  • November 2004

publisher