Structure-assisted functional anchor implantation in robust metal-organic frameworks with ultralarge pores.

abstract

• A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.

authors

• Zhou, Hong-Cai

published proceedings

• J Am Chem Soc

altmetric score

• 1

author list (cited authors)

• Park, J., Feng, D., & Zhou, H.

citation count

• 59

complete list of authors

• Park, Jihye||Feng, Dawei||Zhou, Hong-Cai

publication date

• February 2015

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Boron Compounds
• Fluorescent Dyes
• Iron Compounds
• Ligands
• Models, Molecular
• Organometallic Compounds
• Porosity
• Scandium
• Surface Properties
• Thermodynamics

PubMed Central ID

• 25581395

Digital Object Identifier (DOI)

• 10.1021/ja5123528

start page

• 1663

end page

• 1672

volume

• 137

issue

• 4

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fja5123528