Piezofluorochromic Metal-Organic Framework: A Microscissor Lift.

abstract

• We have successfully constructed a metal-organic framework, denoted as PCN-128W, starting from chromophoric linker and zirconium salt. PCN-128W exhibits interesting piezofluorochromic behavior, the color reversibly changes from white to yellow and so does the emission maximum from 470 to 538 nm. The stepwise fluorescence change was monitored by fluorospectroscopy which demonstrated gradual shift of the emission maximum when sequential compression was exerted. In order to gain deep insights into the piezofluorochromic mechanism, both the white and yellow phases are structurally characterized.

authors

• Zhou, Hong-Cai

published proceedings

• J Am Chem Soc

altmetric score

• 0.5

author list (cited authors)

• Zhang, Q., Su, J., Feng, D., Wei, Z., Zou, X., & Zhou, H.

citation count

• 191

complete list of authors

• Zhang, Qiang||Su, Jie||Feng, Dawei||Wei, Zhangwen||Zou, Xiaodong||Zhou, Hong-Cai

publication date

• August 2015

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 26214704

Digital Object Identifier (DOI)

• 10.1021/jacs.5b04695

start page

• 10064

end page

• 10067

volume

• 137

issue

• 32

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fjacs.5b04695