Investigation of gas adsorption performances and H2 affinities of porous metal-organic frameworks with different entatic metal centers. Academic Article

abstract

• Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H(3)TATB ligand and a novel square-planar secondary building unit. N(2) adsorption isotherms at 77 K confirmed the permanent porosities of the three porous MOFs. Variable-temperature adsorption measurements of H(2) revealed that the H(2) affinities of the three porous MOFs are related to the nature of entatic metal centers, which reversely affect their H(2) uptake capacities.

authors

• Zhou, Hongcai

published proceedings

• Inorg Chem

altmetric score

• 3

author list (cited authors)

• Ma, S., Yuan, D., Chang, J., & Zhou, H.

citation count

• 68

complete list of authors

• Ma, Shengqian||Yuan, Daqiang||Chang, Jong-San||Zhou, Hong-Cai

publication date

• June 2009

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 19456136

Digital Object Identifier (DOI)

• 10.1021/ic900475q

start page

• 5398

end page

• 5402

volume

• 48

issue

• 12

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fic900475q