Crystallographic evidence for chromium-platinum interaction. Academic Article

abstract

• Heteronuclear Pt-Cr paddlewheel complexes with significant Pt-Cr interaction have been made. They can be interconverted. Upon oxidation, the Pt-Cr distance shortens significantly while other bond lengths remain unchanged. By taking into account the strong axial coordination from the chloride ligand in the oxidized compound, we suspect that the removed electron upon oxidation is probably from a Pt-Cr orbital that is significantly antibonding in nature.

authors

• Zhou, Hongcai

published proceedings

• Inorg Chem

author list (cited authors)

• Scott, T. A., Abbaoui, B., & Zhou, H.

citation count

• 15

complete list of authors

• Scott, Thomas A||Abbaoui, Besma||Zhou, Hong-Cai

publication date

• April 2004

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 15074959

Digital Object Identifier (DOI)

• 10.1021/ic049968c

start page

• 2459

end page

• 2461

volume

• 43

issue

• 8

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fic049968c