Construction of two 3D homochiral frameworks with 1D chiral pores via chiral recognition. Academic Article

abstract

• The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)](2)(l-pends)(ClO(4))(2)}(n) (-1) and {[Ni(f-(RR)-L)](2)(d-pends) (ClO(4))(2)}(n) (-1). The frameworks possess 1D tubular pores and opposite right/left-handed helical porous surfaces (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; pends(2-) = penicillaminedisulfide anion).

authors

• Zhou, Hongcai

published proceedings

• Inorg Chem

author list (cited authors)

• Li, H., Jiang, L., Xiang, H., Makal, T. A., Zhou, H., & Lu, T.

citation count

• 23

complete list of authors

• Li, Huan-Yong||Jiang, Long||Xiang, Hua||Makal, Trevor A||Zhou, Hong-Cai||Lu, Tong-Bu

publication date

• April 2011

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 21434680

Digital Object Identifier (DOI)

• 10.1021/ic200264s

start page

• 3177

end page

• 3179

volume

• 50

issue

• 8

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fic200264s