An In Situ One-Pot Synthetic Approach towards Multivariate Zirconium MOFs. Academic Article

abstract

• Chemically highly stable MOFs incorporating multiple functionalities are of great interest for applications under harsh environments. Herein, we presented a facile one-pot synthetic strategy to incorporate multiple functionalities into stable Zr-MOFs from mixed ligands of different geometry and connectivity. Via our strategy, tetratopic tetrakis(4-carboxyphenyl)porphyrin (TCPP) ligands were successfully integrated into UiO-66 while maintaining the crystal structure, morphology, and ultrahigh chemical stability of UiO-66. The amount of incorporated TCPP is controllable. Through various combinations of BDC derivatives and TCPP, 49MOFs with multiple functionalities were obtained. Among them, MOFs modified with FeTCPPCl were demonstrated to be catalytically active for the oxidation of ABTS. We anticipate our strategy to provide a facile route to introduce multiple functionalities into stable Zr-MOFs for a wide variety of potential applications.

authors

• Zhou, Hong-Cai

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 0.25

author list (cited authors)

• Sun, Y., Sun, L., Feng, D., & Zhou, H.

citation count

• 94

complete list of authors

• Sun, Yujia||Sun, Lixian||Feng, Dawei||Zhou, Hong-Cai

publication date

• May 2016

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Mofs
• Multiple Functionalities
• One-pot Synthesis
• Porphyrins
• Zirconium

PubMed Central ID

• 27100570

Digital Object Identifier (DOI)

• 10.1002/anie.201602274

start page

• 6471

end page

• 6475

volume

• 55

issue

• 22

URL

• http%3A%2F%2Fdx.doi.org%2F10.1002%2Fanie.201602274