Heteronuclear chains of four metal atoms including one quadruply bonded dimetal unit. Dichromium and dimolybdenum compounds with appended copper(I) atoms.
Academic Article
Overview
Research
Identity
Additional Document Info
Other
View All
Overview
abstract
It is shown that the M2(DPhIP)4 molecules (M = Cr, Mo; HDPhIP = 2,6-di(phenylimino)piperidine) can each capture two CuI atoms to form molecules with linear Cu...M[symbol: see text] M...Cu chains. In these chains the CuI atoms have only weak interactions with the M atoms (Cr...Cu = 2.628 A; Mo...Cu = 2.615 A) even though their introduction causes marked decreases in the M[symbol: see text]M distances (from 2.265 to 1.906 A for Cr and from 2.114 to 2.078 A for Mo). These seemingly contradictory facts are explained by noting that in the M2(DPhIP)4 molecules there are strong destabilizing (to the M[symbol: see text]M bonds) donor interactions of the dangling nitrogen atoms with the pi* orbitals. When these are eliminated by the introduction of the CuI atoms, the M[symbol: see text]M bonds become stronger and shorter.