Multielectron oxidation in a ferromagnetically coupled dinickel( ii ) triple mesocate Academic Article uri icon

abstract

  • Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as supported by theoretical calculations.

author list (cited authors)

  • Ferrando-Soria, J., Fabelo, O., Castellano, M., Cano, J., Fordham, S., & Zhou, H.

citation count

  • 20

publication date

  • September 2015