Multielectron oxidation in a ferromagnetically coupled dinickel(ii) triple mesocate. Academic Article uri icon

abstract

  • Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as supported by theoretical calculations.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Ferrando-Soria, J., Fabelo, O., Castellano, M., Cano, J., Fordham, S., & Zhou, H.

citation count

  • 23

complete list of authors

  • Ferrando-Soria, Jesús||Fabelo, Oscar||Castellano, María||Cano, Joan||Fordham, Stephen||Zhou, Hong-Cai

publication date

  • September 2015