Metal-organic hendecahedra assembled from dinuclear paddlewheel nodes and mixtures of ditopic linkers with 120 and 90 degrees bend angles.
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abstract
Don't be square: The title cages were synthesized by cooperative assembly of four-connected units and mixtures of two bridging dicarboxylate ligands (see pic-ture). This work may open a new synthetic path towards complex coordination polyhedra that are inaccessible through reported synthetic procedures. 2009 Wiley-VCH Verlag GmbH & Co. KGaA.