Chain packing in ethoxyphenyl-polycarbonate by C-13{H-2} REDOR Academic Article

abstract

• Rotational-echo double-resonance 13 C{ 2 H} NMR has been used to characterize the chain packing in a 13 C, 2 H-labeled ethoxyphenyl-substituted bisphenol A polycarbonate. Approximately 36% of the repeat units are locally ordered, and between 85% and 95% of carbonate linkages are trans. The local order in interchain packing is correlated with the local order of intrachain conformations of the carbonate linkages.

authors

• Wooley, Karen

published proceedings

• MACROMOLECULES

altmetric score

• 0.5

author list (cited authors)

• O'Connor, R. D., Byers, J. A., Arnold, W. D., Oldfield, E., Wooley, K. L., & Schaefer, J.

citation count

• 7

complete list of authors

• O'Connor, RD||Byers, JA||Arnold, WD||Oldfield, E||Wooley, KL||Schaefer, J

publication date

• March 2002

publisher

• American Chemical Society (ACS)  Publisher

published in

• MACROMOLECULES  Journal

keywords

• 34 Chemical Sciences
• 3407 Theoretical And Computational Chemistry

Digital Object Identifier (DOI)

• 10.1021/ma010918q

start page

• 2618

end page

• 2623

volume

• 35

issue

• 7