Chain packing in ethoxyphenyl-polycarbonate by C-13{H-2} REDOR Academic Article uri icon

abstract

  • Rotational-echo double-resonance 13 C{ 2 H} NMR has been used to characterize the chain packing in a 13 C, 2 H-labeled ethoxyphenyl-substituted bisphenol A polycarbonate. Approximately 36% of the repeat units are locally ordered, and between 85% and 95% of carbonate linkages are trans. The local order in interchain packing is correlated with the local order of intrachain conformations of the carbonate linkages.

published proceedings

  • MACROMOLECULES

altmetric score

  • 0.5

author list (cited authors)

  • O'Connor, R. D., Byers, J. A., Arnold, W. D., Oldfield, E., Wooley, K. L., & Schaefer, J.

citation count

  • 7

complete list of authors

  • O'Connor, RD||Byers, JA||Arnold, WD||Oldfield, E||Wooley, KL||Schaefer, J

publication date

  • March 2002