Outer-sphere direction in iridium C-H borylation. Academic Article uri icon

abstract

  • The NHBoc group affords ortho selective C-H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where the N-H proton hydrogen bonds to a boryl ligand oxygen. The regioselectivities are unique and complement those of directed ortho metalations.

author list (cited authors)

  • Roosen, P. C., Kallepalli, V. A., Chattopadhyay, B., Singleton, D. A., Maleczka, R. E., & Smith, M. R

complete list of authors

  • Roosen, Philipp C||Kallepalli, Venkata A||Chattopadhyay, Buddhadeb||Singleton, Daniel A||Maleczka, Robert E||Smith, Milton R

publication date

  • January 1, 2012 11:11 AM