VINYLBORANES AS TRANS-DIHYDROXYETHYLENE EQUIVALENTS FOR DIELS-ALDER REACTIONS Academic Article uri icon

abstract

  • Several vinylboranes were explored as trans-1,2-dihydroxyethylene equivalents for Diels-Alder reactions. Use of the 1,2-bis(boryl)ethylene 4 allows the direct formation of 1,2-dihydroxycyclohexenes in high yield. The 2-phenyldimethylsilylvinylborane 8 is a good alternative that allows for hydroxyl-group differentiation. 1994.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • SINGLETON, D. A., & REDMAN, A. M.

citation count

  • 39

complete list of authors

  • SINGLETON, DA||REDMAN, AM

publication date

  • January 1, 1994 11:11 AM