[3 + 2] Methylenecyclopentane annulations of unactivated and electron-rich olefins with 2-(phenylsulfonyl)-1-methylenecyclopropanes Academic Article uri icon

abstract

  • : The thiyl radical catalyzed reaction of 1 with unactivated and electron-rich olefins affords methylene-cyclopentanes regiospecifically. Using irradiation in the presence of dibutyl disulfide, these reactions can be achieved using equimolar amounts of olefins. © 1990, American Chemical Society. All rights reserved.

author list (cited authors)

  • Singleton, D. A., & Church, K. M.

citation count

  • 41

publication date

  • August 1990