[3+2] METHYLENECYCLOPENTANE ANNULATIONS OF UNACTIVATED AND ELECTRON-RICH OLEFINS WITH 2-(PHENYLSULFONYL)-1-METHYLENECYCLOPROPANES
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: The thiyl radical catalyzed reaction of 1 with unactivated and electron-rich olefins affords methylene-cyclopentanes regiospecifically. Using irradiation in the presence of dibutyl disulfide, these reactions can be achieved using equimolar amounts of olefins. 1990, American Chemical Society. All rights reserved.