VINYLBORANES ARE OMNIPHILIC DIENOPHILES - SOME UNUSUAL AND USEFUL PROPERTIES OF VINYLBORANES IN DIELS-ALDER REACTIONS Academic Article

abstract

• The rate of Diels-Alder reactions with vinyl-9-BBN is uniquely insensitive to diene substituent effects, and high reactivity is observed with both electron-rich and electron-poor dienes. The regioselectivity of these reactions is controlled mainly by steric effects. 1992.

authors

• Singleton, Daniel

published proceedings

• TETRAHEDRON LETTERS

author list (cited authors)

• SINGLETON, D. A., MARTINEZ, J. P., & WATSON, J. V.

citation count

• 35

complete list of authors

• SINGLETON, DA||MARTINEZ, JP||WATSON, JV

publication date

• February 1992

publisher

• Elsevier  Publisher

published in

• Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry  Journal

keywords

• 34 Chemical Sciences
• 3405 Organic Chemistry
• 3407 Theoretical And Computational Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0040-4039(00)91848-3

start page

• 1017

end page

• 1020

volume

• 33

issue

• 8

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fs0040-4039%2800%2991848-3