VINYLBORANES ARE OMNIPHILIC DIENOPHILES - SOME UNUSUAL AND USEFUL PROPERTIES OF VINYLBORANES IN DIELS-ALDER REACTIONS Academic Article uri icon

abstract

  • The rate of Diels-Alder reactions with vinyl-9-BBN is uniquely insensitive to diene substituent effects, and high reactivity is observed with both electron-rich and electron-poor dienes. The regioselectivity of these reactions is controlled mainly by steric effects. 1992.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • SINGLETON, D. A., MARTINEZ, J. P., & WATSON, J. V.

citation count

  • 34

complete list of authors

  • SINGLETON, DA||MARTINEZ, JP||WATSON, JV

publication date

  • January 1, 1992 11:11 AM