Diels-Alder reactions of 2-Alkenylboranes and cis-1-alkenylboranes. Anomalous selectivity that allows a choice of regiochemistry Academic Article uri icon

abstract

  • 2-Alkenyl- and cis-1-alkenylboranes are highly reactive Diels-Alder dienophiles which display unusual selectivity patters. By taking advantage of a reversal of regiochemistry of reaction with alkenyldihalo- versus alkenyldialkylboranes, any desired regioisomeric product may be favored, usually with very high selectivity. © 1993.

author list (cited authors)

  • Singleton, D. A., Kim, K., & Martinez, J. P.

citation count

  • 27

publication date

  • May 1993