DIELS-ALDER REACTIONS OF 2-ALKENYLBORANES AND CIS-1-ALKENYLBORANES - ANOMALOUS SELECTIVITY THAT ALLOWS A CHOICE OF REGIOCHEMISTRY Academic Article uri icon

abstract

  • 2-Alkenyl- and cis-1-alkenylboranes are highly reactive Diels-Alder dienophiles which display unusual selectivity patters. By taking advantage of a reversal of regiochemistry of reaction with alkenyldihalo- versus alkenyldialkylboranes, any desired regioisomeric product may be favored, usually with very high selectivity. 1993.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • SINGLETON, D. A., KIM, K., & MARTINEZ, J. P.

citation count

  • 28

complete list of authors

  • SINGLETON, DA||KIM, K||MARTINEZ, JP

publication date

  • January 1, 1993 11:11 AM