Catalysis by temporary covalent activation. A novel catalysis of unactivated Diels-Alder reactions
- Additional Document Info
- View All
Diels-Alder reactions of cis-2-chlorovinyltributylstannane are greatly accelerated by the presence of catalytic amounts of haloboranes. Mechanistic studies support a mechanism for the catalysis involving an intermediate boron-aclivated dienophile. A similar but simpler catalysis of Diels Alder reactions of unactivated alkynes, via a hydroboration - Diels-Alder - dehydroboration mechanism, is also described.
author list (cited authors)
Singleton, D. A., Leung, S. W., Martinez, J. P., & Lee, Y. K.
complete list of authors
Singleton, DA||Leung, SW||Martinez, JP||Lee, YK