FORMATION OF IONIC TRANSITION-METAL CARBONYL CLUSTER FRAGMENTS BY ION MOLECULE REACTIONS .3. THE HETERONUCLEAR SYSTEMS Academic Article

abstract

• The ion-molecule reaction chemistry of the Co(CO)3(NO)/Ni(CO)4, Co(CO)3(NO)/Fe(CO)5, and Ni(CO)4/Fe(CO)5heteronuclear systems is presented. the relative reaction rate and cluster valence electron deficiency of the ionic cluster fragments are used to estimate the bond order of the ionic cluster fragments. the coordination unsaturation of the Co(CO)3(NO)/Ni(CO)4system is very similar to the coordination unsaturation of the ionic cluster fragments found in the homonuclear Cr(CO)6, Fe(CO)5, Co(CO)3(NO), and Ni(CO)4systems. the ionic cluster fragments formed in the Co(CO)3(NO)/Fe(CO)5and Ni(CO)4/Fe(CO)5systems seem to follow bonding patterns found in heterometallic systems containing Fe(CO)42-. 1987, American Chemical Society. All rights reserved.

authors

• Russell, David

published proceedings

• JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

author list (cited authors)

• FREDEEN, D. A., & RUSSELL, D. H.

citation count

• 17

complete list of authors

• FREDEEN, DA||RUSSELL, DH

publication date

• June 1987

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

Digital Object Identifier (DOI)

• 10.1021/ja00247a013

start page

• 3903

end page

• 3909

volume

• 109

issue

• 13

URL

• http://dx.doi.org/10.1021/ja00247a013