Bimetallic reductive elimination from dinuclear Pd(III) complexes. Academic Article

abstract

• In 2009, we reported C-halogen reductive elimination reactions from dinuclear Pd(III) complexes and implicated dinuclear intermediates in Pd(OAc)(2)-catalyzed C-H oxidation chemistry. Herein, we report results of a thorough experimental and theoretical investigation of the mechanism of reductive elimination from such dinuclear Pd(III) complexes, which establish the role of each metal during reductive elimination. Our results implicate reductive elimination from a complex in which the dinuclear core is intact and suggest that redox synergy between the two metals is responsible for the facile reductive elimination reactions observed.

authors

• Powers, David

published proceedings

• J Am Chem Soc

altmetric score

• 6

author list (cited authors)

• Powers, D. C., Benitez, D., Tkatchouk, E., Goddard, W. A., & Ritter, T.

citation count

• 219

complete list of authors

• Powers, David C||Benitez, Diego||Tkatchouk, Ekaterina||Goddard, William A||Ritter, Tobias

publication date

• October 2010

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Catalysis
• Oxidation-Reduction
• Palladium

PubMed Central ID

• 20858006

Digital Object Identifier (DOI)

• 10.1021/ja1036644

start page

• 14092

end page

• 14103

volume

• 132

issue

• 40